12/28/2016
AlphaDelta updated with new equations:
Pollington AD, Kozdon R, Anovitz LM, Georg RB, Spicuzza MJ, Valley JW (2016) Experimental calibration of silicon and oxygen isotope fractionations between quartz and water at 250 °C by in situ microanalysis of experimental products and application to zoned low δ30Si quartz overgrowths. Chemical Geology 421:127-142.
Fernandez A, van Dijk J, Müller IA, Bernasconi SM (2016) Siderite acid fractionation factors for sealed and open vessel digestions at 70 °C and 100 °C. Chemical Geology 444:180-186. doi: http://dx.doi.org/10.1016/j.chemgeo.2016.10.015.
In addition, the S-isotope fractionations of Sakai (1968) have been recalculated by fitting theoretical data to ln 1000 alpha = a *10^6/T^2+b*10^3/T+c using the lm function of R software.
The oxygen isotope composition of siderites can be used to deduce the paleoenvironmental conditions under which the mineral formed. However, it is not clear whether the published fractionation factors (αCO2-siderite) for the acid digestion of siderites are appropriate for modern “on-line” sample pre...